Intramolecular σ-Bond Metathesis/Protonolysis on Zirconium(IV) and Hafnium(IV) Pyridylamido Olefin Polymerization Catalyst Precursors: Exploring Unexpected Reactivity Paths
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- 作者：Lapo Luconi ; Giuliano Giambastiani ; Andrea Rossin ; Claudio Bianchini ; Agust Lleds
- 刊名：Inorganic Chemistry
- 出版年：2010
- 出版时间：August 2, 2010
- 年：2010
- 卷：49
- 期：15
- 页码：6811-6813
- 全文大小：736K
- 年卷期：v.49,no.15(August 2, 2010)
- ISSN：1520-510X
文摘
A temperature-controlled metathesis/protonolysis takes place on group 4 amidopyridinate polymerization catalyst precursors. Unraveling this unprecedented reactivity path allowed us to highlight the importance of the metal precursor choice while preparing improved catalytic structures or studying new catalytic processes.