A New Strategy to Microporous Polymers: Knitting Rigid Aromatic Building Blocks by External Cross-Linker

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• 作者：Buyi Li ; Ruini Gong ; Wei Wang ; Xin Huang ; Wang Zhang ; Huanmin Li ; Chunxiao Hu ; Bien Tan
• 刊名：Macromolecules
• 出版年：2011
• 出版时间：April 26, 2011
• 年：2011
• 卷：44
• 期：8
• 页码：2410-2414
• 全文大小：809K
• 年卷期：v.44,no.8(April 26, 2011)
• ISSN：1520-5835

文摘

A series of microporous polymers has been obtained via a low-cost versatile strategy, which involves 鈥渒nitting鈥?rigid aromatic building blocks, such as benzene, biphenyl, 1,3,5-triphenylbenzene, methylbenzene, chlorobenzene, and phenol using an external cross-linker. These materials are predominantly microporous and exhibit high surface areas. Moreover, different building blocks can generate materials with different pore structures, functional groups and application properties, which are significant for materials design.