2D-Coordination Polymer Containing Interconnected 82-Membered Organotin Macrocycles

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• 作者：Vadapalli Chandrasekhar ; Chandrajeet Mohapatra
• 刊名：Crystal Growth & Design
• 出版年：2013
• 出版时间：November 6, 2013
• 年：2013
• 卷：13
• 期：11
• 页码：4655-4658
• 全文大小：383K
• 年卷期：v.13,no.11(November 6, 2013)
• ISSN：1528-7505

文摘

A two-dimensional coordination polymer [(n-Bu₃Sn)₄(渭-L)₂(4,4鈥?bipy)]_n (1) was prepared in a reaction between (n-Bu₃Sn)₂O, (E)-5-(pyridin-4-yl-methyleneamino)isophthalic acid (LH₂), and 4,4鈥?bipyridine (4,4鈥?bipy). The structure of 1 is built by the interlinking of 82-membered macrocyles. The generation of the 2D coordination polymer is facilitated by the multisite coordination capability of the dianionic ligand (L^{2鈥?/sup>) as well as involvement of 4,4鈥?bipyridine as an ancillary ligand.}