Toward the Development of Molecular Wires: A Terpyridine Spacer Containing Polyferrocenylalkyne Linkages

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• 作者：Teng-Yuan Dong ; Shu-Wei Chang ; Shu-Fan Lin ; Mei-Ching Lin ; Yuh-Sheng Wen ; and Liangshiu Lee
• 刊名：Organometallics
• 出版年：2006
• 出版时间：April 10, 2006
• 年：2006
• 卷：25
• 期：8
• 页码：2018 - 2024
• 全文大小：246K
• 年卷期：v.25,no.8(April 10, 2006)
• ISSN：1520-6041

文摘

The preparation, characterizations, and electrochemical measurements of the terpyridine-ferrocenylalkynespacers (tpy-Cmages/entities/tbd1.gif">C-(fc)_n-Cmages/entities/tbd1.gif">C-tpy; tpy = terpyridyl; fc = ferrocenyl; n = 2, 3) are described. In theelectrochemical measurements, the charge could be delocalized to the cyclopentadienyl and ethynylmoieties caused by the built-up charge density upon oxidation of the ferrocenyl moiety.