Synthesis and Characterization of Isomerically Pure anti- and syn-Anthradiindole Derivatives

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• 作者：Jean-Yves Balandier ; Nicolas Henry ; Jean-Baptiste Arlin ; Lionel Sanguinet ; Vincent Lemaur ; Claude Niebel ; Basab Chattopadhyay ; Alan Robert Kennedy ; Philippe Leriche ; Philippe Blanchard ; J茅r么me Cornil ; Yves Henri Geerts
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：January 18, 2013
• 年：2013
• 卷：15
• 期：2
• 页码：302-305
• 全文大小：246K
• 年卷期：v.15,no.2(January 18, 2013)
• ISSN：1523-7052

文摘

Synthesis, isolation, and characterization of isomerically pure syn- and anti-anthradiindole (ADI) derivatives are described. The anti- and syn-ADI structures are demonstrated by ¹³C NMR spectroscopy and by single-crystal X-ray diffraction. The spectroscopic and electrochemical properties as well as the stability of these newly synthesized 蟺-conjugated systems are evaluated and supported by quantum-chemical calculations.