Switching of Slow Magnetic Relaxation Dynamics in Mononuclear Dysprosium(III) Compounds with Charge Density
详细信息 查看全文
- 作者：Kwang Soo Lim ; José J. Baldoví ; Woo Ram Lee ; Jeong Hwa Song ; Sung Won Yoon ; Byoung Jin Suh ; Eugenio Coronado ; Alejandro Gaita-Ariño ; Chang Seop Hong
- 刊名：Inorganic Chemistry
- 出版年：2016
- 出版时间：June 6, 2016
- 年：2016
- 卷：55
- 期：11
- 页码：5398-5404
- 全文大小：449K
- 年卷期：0
- ISSN：1520-510X
文摘
The symmetry around a Dy ion is recognized to be a crucial parameter dictating magnetization relaxation dynamics. We prepared two similar square-antiprismatic complexes, [Dy(LOMe)2(H2O)2](PF6) (1) and Dy(LOMe)2(NO3) (2), where LOMe = [CpCo{P(O)(O(CH3))2}3], including either two neutral water molecules (1) or an anionic nitrate ligand (2). We demonstrated that in this case relaxation dynamics is dramatically affected by the introduction of a charged ligand, stabilizing the easy axis of magnetization along the nitrate direction. We also showed that the application of either a direct-current field or chemical dilution effectively stops quantum tunneling in the ground state of 2, thereby increasing the relaxation time by over 3 orders of magnitude at 3.5 K.