Analytical Characterization of Size-Dependent Properties of Larger Aqueous Gold Nanoclusters

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• 作者：Germán Plascencia-Villa ; Borries Demeler ; Robert L. Whetten ; Wendell P. Griffith ; Marcos Alvarez ; David M. Black ; Miguel José-Yacamán
• 刊名：Journal of Physical Chemistry C
• 出版年：2016
• 出版时间：April 28, 2016
• 年：2016
• 卷：120
• 期：16
• 页码：8950-8958
• 全文大小：472K
• 年卷期：0
• ISSN：1932-7455

文摘

Gold nanoclusters (AuNCs) with well-defined structure and arrangement possess particular physical and functional properties. AuNCs that differ only by less than 1 nm in diameter corresponding to one atomic layer show different structural, optical, and physicochemical properties in a size-dependent mode, making their analytical characterization a challenge. Herein we describe an integrative approach to characterization of larger aqueous AuNC (Au₁₀₂-pMBA₄₄, Au₁₄₄pMBA₆₀ and higher) selected by gel electrophoresis (PAGE). We employ UV–vis, dynamic light scattering, and zeta-potential in combination with high-performance analytical techniques such as multiwavelength analytical ultracentrifugation and electrospray ionization mass spectrometry were used to separate aqueous AuNCs and to determine their specific hydrodynamic diameter, partial abundance, molecular weight, and mass/charge ratios when present in a complex mixture of AuNCs containing Au₁₀₂ (1.6 nm), Au₁₄₄ (2 nm), and Au_288–328 (2.5 nm). Advanced analytical electron microscopy imaging (spherical aberration corrected BF/HAADF-STEM at low voltages dose) also revealed the structures of discrete arrangements of gold nanocluster populations.