Fluorination of Epitaxial Oxides: Synthesis of Perovskite Oxyfluoride Thin Films
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- 作者：Eun Ju Moon ; Yujun Xie ; Eric D. Laird ; David J. Keavney ; Christopher Y. Li ; Steven J. May
- 刊名：Journal of the American Chemical Society
- 出版年：2014
- 出版时间：February 12, 2014
- 年：2014
- 卷：136
- 期：6
- 页码：2224-2227
- 全文大小：328K
- ISSN：1520-5126
文摘
While the synthesis of ABO3 perovskite films has enabled new strategies to control the functionality of this material class, the chemistries that have been realized in thin film form constitute only a fraction of those accessible to bulk chemists. Here, we report the synthesis of oxyfluoride films, where the incorporation of F may provide a new means to tune physical properties in thin films by modifying electronic structure. Fluorination is achieved by spin coating a poly(vinylidene fluoride) (PVDF) solution onto oxygen-deficient films. The film/polymer bilayer is then annealed, promoting the diffusion of F into the film. We have used this method to synthesize SrFeO3-伪F纬 films, as confirmed by X-ray photoemission spectroscopy and X-ray absorption spectroscopy.