Sulfur K-Edge XAS as a Probe of Sulfur-Centered Radical Intermediates

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• 作者：Vlad Martin-Diaconescu ; Pierre Kennepohl
• 刊名：Journal of the American Chemical Society
• 出版年：2007
• 出版时间：March 21, 2007
• 年：2007
• 卷：129
• 期：11
• 页码：3034 - 3035
• 全文大小：68K
• 年卷期：v.129,no.11(March 21, 2007)
• ISSN：1520-5126

文摘

Sulfur K-edge XAS is used in the identification and characterization of sulfur based radicals obtained from UV irradiated glutathione. Ground state and time-dependent DFT calculations are used to identify thiyl (RS) and perthiyl (RSS) radical species.