Redox-Switchable Hydroelementation of a Cobalt Complex Supported by a Ferrocene-Based Ligand

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• 作者：Scott M. Shepard ; Paula L. Diaconescu
• 刊名：Organometallics
• 出版年：2016
• 出版时间：August 8, 2016
• 年：2016
• 卷：35
• 期：15
• 页码：2446-2453
• 全文大小：436K
• 年卷期：0
• ISSN：1520-6041

文摘

The first crystallographically characterized tetrahedral cobalt salen (salen = N,N′-ethylenesalicylimine) complex was synthesized by using a 1,1′-ferrocene derivative, salfen (salfen = 1,1′- di(2,4-di-tert-butyl-6-salicylimine)ferrocene). The complex undergoes two oxidation events at low potentials, which were assigned as ligand centered by comparison to the corresponding zinc complex. The cobalt complex was found to catalyze the hydroalkoxylation of styrenes, similarly to related square planar cobalt salen complexes, likely due to its fluxional behavior in alcoholic solvents. Furthermore, the one-electron-oxidized species was found to be inactive toward hydroalkoxylation. Thus, the hydroalkoxylation reactivity could be turned on/off in situ by redox chemistry.