Silyl Phosphorus and Nitrogen Donor Chelates for Homogeneous Ortho Borylation Catalysis

详细信息    查看全文

• 作者：Behnaz Ghaffari ; Sean M. Preshlock ; Donald L. Plattner ; Richard J. Staples ; Peter E. Maligres ; Shane W. Krska ; Robert E. Maleczka ; Jr. ; Milton R. Smith ; III
• 刊名：Journal of the American Chemical Society
• 出版年：2014
• 出版时间：October 15, 2014
• 年：2014
• 卷：136
• 期：41
• 页码：14345-14348
• 全文大小：350K
• ISSN：1520-5126

文摘

Ir catalysts supported by bidentate silyl ligands that contain P- or N-donors are shown to effect ortho borylations for a range of substituted aromatics. The substrate scope is broad, and the modular ligand synthesis allows for flexible catalyst design.