On-Demand Cyclophanes: Substituent-Directed Self-Assembling, Folding, and Binding
详细信息 查看全文
- 作者：Pierre-Thomas Skowron ; Melissa Dumartin ; Emeric Jeamet ; Florent Perret ; Christophe Gourlaouen ; Anne Baudouin ; Bernard Fenet ; Jean-Valère Naubron ; Frédéric Fotiadu ; Laurent Vial ; Julien Leclaire
- 刊名：Journal of Organic Chemistry
- 出版年：2016
- 出版时间：January 15, 2016
- 年：2016
- 卷：81
- 期：2
- 页码：654-661
- 全文大小：418K
- ISSN：1520-6904
文摘
A family of p-cyclophanes based on bis- or tetrafunctionalized 1,4-bisthiophenol units linked by disulfide bridges was obtained by self-assembly on a gram scale and without any chromatographic purification. The nature of the functionalities borne by these so-called dyn[4]arenes plays a crucial role on their structural features as well as their molecular recognition abilities. Tuning these functions on demand yields tailored receptors for cations, anions, or zwitterions in organic or aqueous media.