Unimolecular Micelles from Layered Amphiphilic Dendrimer-Like Block Copolymers

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• 作者：Yunpeng Wang ; Gang Qi ; Junpo He
• 刊名：ACS Macro Letters
• 出版年：2016
• 出版时间：April 19, 2016
• 年：2016
• 卷：5
• 期：4
• 页码：547-551
• 全文大小：351K
• 年卷期：0
• ISSN：2161-1653

文摘

In this report, we synthesized layered amphiphilic dendrimer-like block copolymers containing a polystyrene core and poly(p-tert-butoxystyrene)/poly(p-hydroxylstyrene) shell (coded G4-PtBOS/G4-PHOS). The synthetic method is easy involving anionic polymerization, epoxidation, ring-opening reaction and hydrolysis reaction. The hydrolyzed G4-PtBOS was soluble in alkaline water and behaved as unimolecular micelle, as demonstrated by the results of DLS, cryo- and normal TEM, and pyrene entrapping experiment. The stability of the unimolecular micelles was investigated via ζ-potential measurements.