Facile Synthesis of the Tridecameric Al13 Nanocluster Al13(μ3-OH)6(μ2-OH)18(H2O)24(NO3)
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- 作者：Jason T. Gatlin ; Zachary L. Mensinger ; Lev N. Zakharov ; David MacInnes ; Darren W. Johnson
- 刊名：Inorganic Chemistry
- 出版年：2008
- 出版时间：February 18, 2008
- 年：2008
- 卷：47
- 期：4
- 页码：1267 - 1269
- 全文大小：293K
- 年卷期：v.47,no.4(February 18, 2008)
- ISSN：1520-510X
文摘
Treatment of aluminum nitrate with an organic nitroso-containing compound yields the “flat”, tridecameric nanocluster Al13(μ3-OH)6(μ2-OH)18(H2O)24(NO3)15 (Al13) in good yield on a preparative scale under ambient conditions. Synthetic procedures yielding two different single-crystal forms of the Al13 cation with two varying counterion compositions are described.