Green Diacetoxylation of Alkenes in a Microchemical System

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• 作者：Jeong Hyeon Park ; Chan Yi Park ; Hyun Seung Song ; Yun Suk Huh ; Geon Hee Kim ; Chan Pil Park
• 刊名：Organic Letters
• 出版年：2013
• 出版时间：February 15, 2013
• 年：2013
• 卷：15
• 期：4
• 页码：752-755
• 全文大小：240K
• 年卷期：v.15,no.4(February 15, 2013)
• ISSN：1523-7052

文摘

The palladium-catalyzed diacetoxylation and trifluoromethanesulfonic acid-catalyzed diacetoxylation using inexpensive and environmentally friendly hydrogen peroxide and peracetic acid were successfully conducted with the help of microchemical technology. Excellent yield and selectivity were achieved in significantly shortened reaction times without the decomposition of explosive oxidants and further transformation of unstable products, offering a safe and efficient alternative to traditional methods for alkene diacetoxylation.