Triacetonide of Glucoheptonic Acid in the Scalable Syntheses of d-Gulose, 6-Deoxy-d-gulose, l-Glucose, 6-Deoxy-l-glucose, and Related Sugars
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- 作者：Zilei Liu ; Akihide Yoshihara ; Sarah F. Jenkinson ; Mark R. Wormald ; Ramón J. Estévez ; George W. J. Fleet ; Ken Izumori
- 刊名：Organic Letters
- 出版年：2016
- 出版时间：August 19, 2016
- 年：2016
- 卷：18
- 期：16
- 页码：4112-4115
- 全文大小：343K
- 年卷期：0
- ISSN：1523-7052
文摘
Ease of separation of petrol-soluble acetonides derived from the triacetonide of methyl glucoheptonate allows scalable syntheses of rare sugars containing the l-gluco or d-gulo structural motif with any oxidation level at the C6 or C1 position of the hexose, usually without chromatography: meso-d-glycero-d-guloheptitol available in two steps is an ideal entry point for the study of the biotechnological production of heptoses.