Uncommon Ferromagnetic Interactions in a Homometallic Co(II) Chain Bridged by a Single End-to-End Azide

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• 作者：Houng Sik Yoo ; Jae Il Kim ; Namgeun Yang ; Eui Kwan Koh ; Je-Geun Park ; Chang Seop Hong
• 刊名：Inorganic Chemistry
• 出版年：2007
• 出版时间：October 29, 2007
• 年：2007
• 卷：46
• 期：22
• 页码：9054 - 9056
• 全文大小：105K
• 年卷期：v.46,no.22(October 29, 2007)
• ISSN：1520-510X

文摘

A new one-dimensional heterochiral coordination polymer[Co(bmdt)(N<SUB>3)₂]·MeCN (1·MeCN) with well-isolated chains wasprepared via a self-assembly process. Magnetic data show thatintrachain ferromagnetic couplings via the single end-to-end azidegroup are observed, which is an extraordinary case among theazide-bridged Co(II) systems.