Partial Oxidation of Methane in a Catalytic Ruthenium Membrane Reactor
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- 作者：Luca Paturzo ; Fausto Gallucci ; Angelo Basile ; Paolo Pertici ; Nico Scalera ; and Giovanni Vitulli
- 刊名：Industrial & Engineering Chemistry Research
- 出版年：2003
- 出版时间：June 25, 2003
- 年：2003
- 卷：42
- 期：13
- 页码：2968 - 2974
- 全文大小：264K
- 年卷期：v.42,no.13(June 25, 2003)
- ISSN：1520-5045
文摘
A catalytic ruthenium membrane reactor (CRMR) is analyzed with regard to the methane partialoxidation reaction for synthesis gas production. The catalytic membrane consists of a commercialceramic tube, where two different layers of ruthenium nanoparticles have been deposited onthe inner surface. The metal deposition was performed by decomposition of a Ru complex undermild conditions. Different operating modes are analyzed for CRMR to establish the potentialityof the Ru catalyst deposited on the tubular ceramic support. A comparison in terms of methaneconversion at various temperatures is presented. Experimental runs of CRMR containing a one-Ru-layer membrane and a two-Ru-layer membrane have also been compared.