Selective, Tunable O2 Binding in Cobalt(II)–Triazolate/Pyrazolate Metal–Organic Frameworks

详细信息    查看全文

• 作者：Dianne J. Xiao ; Miguel I. Gonzalez ; Lucy E. Darago ; Konstantinos D. Vogiatzis ; Emmanuel Haldoupis ; Laura Gagliardi ; Jeffrey R. Long
• 刊名：Journal of the American Chemical Society
• 出版年：2016
• 出版时间：June 8, 2016
• 年：2016
• 卷：138
• 期：22
• 页码：7161-7170
• 全文大小：548K
• 年卷期：0
• ISSN：1520-5126

文摘

The air-free reaction of CoCl₂ with 1,3,5-tri(1H-1,2,3-triazol-5-yl)benzene (H₃BTTri) in N,N-dimethylformamide (DMF) and methanol leads to the formation of Co-BTTri (Co₃[(Co₄Cl)₃(BTTri)₈]₂·DMF), a sodalite-type metal–organic framework. Desolvation of this material generates coordinatively unsaturated low-spin cobalt(II) centers that exhibit a strong preference for binding O₂ over N₂, with isosteric heats of adsorption (Q_st) of −34(1) and −12(1) kJ/mol, respectively. The low-spin (S = 1/2) electronic configuration of the metal centers in the desolvated framework is supported by structural, magnetic susceptibility, and computational studies. A single-crystal X-ray structure determination reveals that O₂ binds end-on to each framework cobalt center in a 1:1 ratio with a Co–O₂ bond distance of 1.973(6) Å. Replacement of one of the triazolate linkers with a more electron-donating pyrazolate group leads to the isostructural framework Co-BDTriP (Co₃[(Co₄Cl)₃(BDTriP)₈]₂·DMF; H₃BDTriP = 5,5′-(5-(1H-pyrazol-4-yl)-1,3-phenylene)bis(1H-1,2,3-triazole)), which demonstrates markedly higher yet still fully reversible O₂ affinities (Q_st = −47(1) kJ/mol at low loadings). Electronic structure calculations suggest that the O₂ adducts in Co-BTTri are best described as cobalt(II)–dioxygen species with partial electron transfer, while the stronger binding sites in Co-BDTriP form cobalt(III)–superoxo moieties. The stability, selectivity, and high O₂ adsorption capacity of these materials render them promising new adsorbents for air separation processes.