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Abyssomicin E, a Highly Functionalized Polycyclic Metabolite from Streptomyces Species
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Abyssomicin E (1), a new polycyclic metabolite with a C19 skeleton, was isolated from Streptomyces sp. (HKI0381). Its chemical structure wasdetermined by comprehensive NMR and MS spectroscopic analyses. For the first time in this recently discovered class of compounds, theabsolute stereochemistry was directly established by subsequent single-crystal X-ray diffraction study using anomalous dispersion with copperradiation.

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