Formation and Growth of Image Crystals by Helium Precipitation

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• 作者：Hiroyuki Serizawa ; Junji Matsunaga ; Yoshinori Haga ; Kunihisa Nakajima ; Mitsuo Akabori ; Tomohito Tsuru ; Yoshiyuki Kaji ; Shinji Kashibe ; Yuji Ohisi ; Shinsuke Yamanaka
• 刊名：Crystal Growth & Design
• 出版年：2013
• 出版时间：July 3, 2013
• 年：2013
• 卷：13
• 期：7
• 页码：2815-2823
• 全文大小：524K
• 年卷期：v.13,no.7(July 3, 2013)
• ISSN：1528-7505

文摘

We found that porous UO₂ grain was formed by the precipitation of helium injected by HIP. Scanning electron microscopy analysis showed that polyhedral negative crystals were formed in the sample. The shape of the negative crystal changes dramatically with the conditions of helium precipitation. A truncated octahedron-type, an octa-triacontahedron-type, and a pentacontahedron-type negative crystal were observed. Our study implies that the shape of the negative crystal should change depending on the helium inner pressure enclosed in the negative crystal. It is difficult to arbitrarily control the shapes of these polyhedral negative crystals embedded in a solid medium. However, the shape of the negative crystal can easily be controlled by the helium injection method. In this article, we call the shape controlled negative crystal an image crystal. Here, we report a relationship between the surface energy and the shape and discuss the transformation mechanism of the image crystal. Our detailed observation indicates that the growth process of the image crystal can be explained by a step free energy model rather than an attachment energy. We could not find a cuboctahedron-type negative crystal of which the surface area is larger than that of a pentacontahedron-type negative crystal with the same volume.