Solubility of CO2, H2S, and Their Mixture in the Ionic Liquid 1-Octyl-3-methylimidazolium Bis(trifluoromethyl)sulfonylimide

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• 作者：Amir Hossein Jalili ; Mohammadali Safavi ; Cyrus Ghotbi ; Ali Mehdizadeh ; Masih Hosseini-Jenab ; Vahid Taghikhani
• 刊名：The Journal of Physical Chemistry B
• 出版年：2012
• 出版时间：March 8, 2012
• 年：2012
• 卷：116
• 期：9
• 页码：2758-2774
• 全文大小：564K
• 年卷期：v.116,no.9(March 8, 2012)
• ISSN：1520-5207

文摘

Gaseous solubilities of carbon dioxide (1), hydrogen sulfide (2), and their binary mixture (x₂ 鈮?0.2, 0.5, 0.8) have been measured in the ionic liquid 1-octyl-3-methylimidazolium bis(trifluoromethyl)sulfonylimide ([C₈mim][Tf₂N]) at temperatures ranging from (303.15 to 353.15) K and at pressures under 2 MPa. The observed PTx solubility data were used to obtain Henry's law constants and correlated by three models: (1) the simple Krichevsky鈥揔asarnovsky (KK) equation, (2) a model comprised of the extended Henry's law and the Pitzer's virial expansion for the excess Gibbs free energy, and (3) the generic Redlich鈥揔wong (RK) cubic equation of state proposed for gas鈥搃onic liquid systems. The correlations from the three models show quite good consistency with the experimental data for IL/CO₂ and IL/H₂S binary mixtures within experimental uncertainties. For IL/CO₂/H₂S ternary mixtures, the RK model shows the best correlation with the experimental data. The comparison showed that the solubility of H₂S is about two times as great as that of CO₂ in the ionic liquid studied in this work. It was further found, by comparison of the experimental data of this study with those of previous reports, that the solubility of H₂S in [C_nmim][Tf₂N] ILs increases as the number of carbon atoms in the alkyl substituent of methylimidazolium cation, n, increases. In addition, quantum chemical calculations at DFT/B3LYP level of theory using 6-311+G(d) and 6-311++G(2d,2p) basis sets were performed on the isolated systems studied in this work to provide explanations from a molecular point of view for the observed experimental trends.