Reduction of Hydroxylated Fullerene (Fullerol) in Water by Zinc: Reaction and Hemiketal Product Characterization

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• 作者：Jiewei Wu ; Lawrence B. Alemany ; Wenlu Li ; Liza Petrie ; Cara Welker ; John D. Fortner
• 刊名：Environmental Science & Technology
• 出版年：2014
• 出版时间：July 1, 2014
• 年：2014
• 卷：48
• 期：13
• 页码：7384-7392
• 全文大小：443K
• ISSN：1520-5851

文摘

Water-soluble, hydroxylated fullerene (fullerol) materials have recently gained increasing attention as they have been identified as the primary product(s) during the exposure of fullerenes (as water stable, nanoscale aggregated C₆₀) to UV light in water. The physical properties and chemical reactivity of resulting fullerols, however, have not been thoroughly studied. In this paper, we identified and characterized the reductive transformation of fullerol (C₆₀(OH)_x(ONa)_y) by solid zinc metal (Zn(0)) through a series of batch reaction experiments and product characterization, including ¹³C NMR, FTIR, XPS, UV-vis, DLS, and TEM. Results indicated the facile formation of water stable, pH sensitive hemiketal functionality as part of a relatively reduced fullerol product. Further, aqueous physical behavior of the product fullerol, as measured by octanol partitioning and surface deposition rates, was observed to significantly differ from the parent material and is consistent with a relative increase in molecular (product) hydrophobicity.