Copper-Catalyzed Methyl Esterification Reactions via C鈥揅 Bond Cleavage

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• 作者：Yan Zhu ; Hong Yan ; Linhua Lu ; Defu Liu ; Guangwei Rong ; Jincheng Mao
• 刊名：Journal of Organic Chemistry
• 出版年：2013
• 出版时间：October 4, 2013
• 年：2013
• 卷：78
• 期：19
• 页码：9898-9905
• 全文大小：505K
• 年卷期：v.78,no.19(October 4, 2013)
• ISSN：1520-6904

文摘

The highly effective synthesis of methyl esters from benzylic alcohols, aldehydes, or acids via copper-catalyzed C鈥揅 cleavage from tert-butyl hydroperoxide is reported in this paper for the first time. Our protocol is easily accessible and practical, making it a possible supplement for the traditional way.