Design and Synthesis of Two Porous Metal鈥揙rganic Frameworks with nbo and agw Topologies Showing High CO2 Adsorption Capacity

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• 作者：Zhiqiang Liang ; Jingjing Du ; Libo Sun ; Jin Xu ; Ying Mu ; Yi Li ; Jihong Yu ; Ruren Xu
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：October 7, 2013
• 年：2013
• 卷：52
• 期：19
• 页码：10720-10722
• 全文大小：236K
• 年卷期：v.52,no.19(October 7, 2013)
• ISSN：1520-510X

文摘

Two novel porous copper-based metal鈥搊rganic frameworks with nbo and agw topologies have been designed and synthesized using tetracarboxylate and tricarboxylate ligands, respectively. They possess large surface areas and high CO₂ adsorption capacities (up to 170 cm³/g or 7.59 mmol/g at 0 掳C under ambient pressure).