Noncovalent Functionalization of Graphene and Graphene Oxide for Energy Materials, Biosensing, Catalytic, and Biomedical Applications

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• 作者：Vasilios Georgakilas ; Jitendra N. Tiwari ; K. Christian Kemp ; Jason A. Perman ; Athanasios B. Bourlinos ; Kwang S. Kim ; Radek Zboril
• 刊名：Chemical Reviews
• 出版年：2016
• 出版时间：May 11, 2016
• 年：2016
• 卷：116
• 期：9
• 页码：5464-5519
• 全文大小：3564K
• 年卷期：0
• ISSN：1520-6890

文摘

This Review focuses on noncovalent functionalization of graphene and graphene oxide with various species involving biomolecules, polymers, drugs, metals and metal oxide-based nanoparticles, quantum dots, magnetic nanostructures, other carbon allotropes (fullerenes, nanodiamonds, and carbon nanotubes), and graphene analogues (MoS₂, WS₂). A brief description of π–π interactions, van der Waals forces, ionic interactions, and hydrogen bonding allowing noncovalent modification of graphene and graphene oxide is first given. The main part of this Review is devoted to tailored functionalization for applications in drug delivery, energy materials, solar cells, water splitting, biosensing, bioimaging, environmental, catalytic, photocatalytic, and biomedical technologies. A significant part of this Review explores the possibilities of graphene/graphene oxide-based 3D superstructures and their use in lithium-ion batteries. This Review ends with a look at challenges and future prospects of noncovalently modified graphene and graphene oxide.