A Crystallizable Dinuclear Tuck-In-Tuck-Over Tuck-Over Dialkyl Tren Uranium Complex and Double Dearylation of BPh4− To Give the BPh2-Functionalized Metallocycle

详细信息    查看全文

• 作者：Benedict M. Gardner ; Jonathan McMaster ; William Lewis ; Alexander J. Blake ; Stephen T. Liddle
• 刊名：Journal of the American Chemical Society
• 出版年：2009
• 出版时间：August 5, 2009
• 年：2009
• 卷：131
• 期：30
• 页码：10388-10389
• 全文大小：154K
• 年卷期：v.131,no.30(August 5, 2009)
• ISSN：1520-5126

文摘

The unprecedented formation of a dinuclear tuck-in-tuck-over tuck-over dialkyl Tren-uranium(IV) complex and the first example of double dearylation of BPh₄⁻ in a molecular context to give a BPh₂-functionalized uranium metallocycle are reported.