Styrene as 4π-Component in Zn(II)-Catalyzed Intermolecular Diels–Alder/Ene Tandem Reaction

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• 作者：Min Zheng ; Feng Wu ; Kai Chen ; Shifa Zhu
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：August 5, 2016
• 年：2016
• 卷：18
• 期：15
• 页码：3554-3557
• 全文大小：359K
• 年卷期：0
• ISSN：1523-7052

文摘

A mild Zn-catalyzed intermolecular Diels–Alder/ene tandem reaction with styrene as a 4π-component is reported. A variety of dihydronaphthalene products could be prepared in moderate to good yields. Moreover, a combination of DFT calculations and experiments was performed to further understand the mechanism of this unique tandem reaction.