Poly(vinylidene fluoride) Membranes with Hyperbranched Antifouling and Antibacterial Polymer Brushes
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- 作者：Tao Cai ; Wen Jing Yang ; Koon-Gee Neoh ; En-Tang Kang
- 刊名：Industrial & Engineering Chemistry Research
- 出版年：2012
- 出版时间：December 12, 2012
- 年：2012
- 卷：51
- 期：49
- 页码：15962-15973
- 全文大小：813K
- 年卷期：v.51,no.49(December 12, 2012)
- ISSN：1520-5045
文摘
Graft copolymers of poly(vinylidene fluoride) (PVDF) with poly[2-(N,N-dimethylamino)ethyl methacrylate] (PDMAEMA) side chains (PVDF-g-PDMAEMA copolymers) were synthesized via activators generated by electron transfer for atom transfer radical polymerization (AGET-ATRP) of 2-(N,N-dimethylamino)ethyl methacrylate (DMAEMA) directly from the secondary fluorine atoms on the PVDF backbone. Microporous membranes were fabricated from the PVDF-g-PDMAEMA amphiphilic copolymers by phase inversion in an aqueous medium. After quaternization by propargyl bromide, the resulting PVDF-g-PQDMAEMA membrane and pore surfaces bearing pendant propargyl moieties could be further functionalized via surface-initiated alkyne鈥揳zide click reaction of azido-terminated hyperbranched polyglycerols (HPG-N3) to form the PVDF-g-P[QDMAEMA-click-HPG] membranes. The PVDF-g-P[QDMAEMA-click-HPG] membranes exhibit good resistance to protein adsorption and fouling. Alternatively, alkyne鈥揳zide click reaction of azido-terminated polyethylenimine (PEI-N3) on the PVDF-g-PQDMAEMA membranes, followed by quaternization with 1-bromohexane, produce the PVDF-g-P[QDMAEMA-click-QPEI] membrane which is effective in reducing bacterial growth and proliferation under continuous-flow conditions.