Convenient Controlled Aqueous C1 Synthesis of Long-Chain Aliphatic AB, AA, and BB Macromonomers for the Synthesis of Polyesters with Tunable Hydrocarbon Chain Segments

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• 作者：Ruobing Zhao ; Yan Zhang ; Jaeyoon Chung ; Kenneth J. Shea
• 刊名：ACS Macro Letters
• 出版年：2016
• 出版时间：July 19, 2016
• 年：2016
• 卷：5
• 期：7
• 页码：854-857
• 全文大小：255K
• 年卷期：0
• ISSN：2161-1653

文摘

The insertion of long hydrocarbon chains between ester groups in polyester allows for introduction and modulation of crystallinity, which can result in enhanced performance approaching high-density polyethylene. We report a convenient synthesis of building blocks for long-chain aliphatic polyesters via an aqueous C1 polymerization. The macromonomers include ω-hydroxyacid esters, α,ω-diols and α,ω-diacids. The length of hydrocarbon chain segment (C20–C60) can be controlled by the ratio of monomer/initiator in the C1 polymerization. The obtained polyesters from condensation of the long-chain ω-hydroxyacid esters have thermal and mechanical properties indistinguishable from related materials derived from biomass.