Highly Regio- and Stereoselective One-Pot Synthesis of Carbohydrate-Based Butyrolactones

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• 作者：Syed Khalid Yousuf ; Debaraj Mukherjee ; Mallikharjunrao L ; Subhash C. Taneja
• 刊名：Organic Letters
• 出版年：2011
• 出版时间：February 18, 2011
• 年：2011
• 卷：13
• 期：4
• 页码：576-579
• 全文大小：750K
• 年卷期：v.13,no.4(February 18, 2011)
• ISSN：1523-7052

文摘

The use of manganese(III) acetate allows the direct synthesis of diverse arrays of [4.3.0] bicyclic carbohydrate-based 纬-lactone building blocks from glycals. A mechanism to explain the high regio- and stereoselectivity is proposed. The new reaction has the potential to generate libraries for biological screening.