The nonionic, red-emitting complexes [Os(fppz)
2L
2] (L = PPh
2Me (
1), PPhMe
2 (
2)) and [Os(bptz)
2L
2] (L = PPh
2Me (
3)) were synthesized, showinghighly intense red phosphorescent emission in CH
2Cl
2solution at
max 617, 632, and 649 nm, respectively. Theelectroluminescent properties of these compounds onOLEDs showed promising device efficiencies required forfuture OLED applications.