Defect Engineering of Lead-Free Piezoelectrics with High Piezoelectric Properties and Temperature-Stability

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• 作者：Yu Feng ; Wei-Li Li ; Dan Xu ; Yu-Long Qiao ; Yang Yu ; Yu Zhao ; Wei-Dong Fei
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：April 13, 2016
• 年：2016
• 卷：8
• 期：14
• 页码：9231-9241
• 全文大小：752K
• 年卷期：0
• ISSN：1944-8252

文摘

The high piezoelectricity of ABO₃-type lead-free piezoelectric materials can be achieved with the help of either morphotropic phase boundary (MPB) or polymorphic phase transition (PPT). Here, we propose a new defect engineering route to the excellent piezoelectric properties, in which doped smaller acceptor and donor ions substituting bivalent A-sites are utilized to bring local lattice distortion and lower symmetry. A concrete paradigm is presented, (Li–Al) codoped BaTiO₃ perovskite, that exhibits a largely thermo-stable piezoelectric constant (>300 pC/N) and huge mechanical quality factor (>2000). A systematic analysis including theoretical analysis and simulation results indicates that the Li⁺ and Al³⁺ ions are inclined to occupy the neighboring A-sites in the lattice and constitute a defect dipole (ionic pairs). The defect dipoles possess a kind of dipole moment which tends to align directionally after thermo-electric treatment. A mechanism related to the defect symmetry principle, phase transition, and defect migration is proposed to explain the outstanding piezoelectric properties. The present study opens a new development window for excellent piezoelectricity and provides a promising route to the potential utilization of lead-free piezoelectrics in high power applications.