N-Benzyl-2,3-oxazolidinone as a Glycosyl Donor for Selective -Glycosylation and One-Pot Oligosaccharide Synthesis Involving 1

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• 作者：Shino Manabe ; Kazuyuki Ishii ; Yukishige Ito
• 刊名：Journal of the American Chemical Society
• 出版年：2006
• 出版时间：August 23, 2006
• 年：2006
• 卷：128
• 期：33
• 页码：10666 - 10667
• 全文大小：66K
• 年卷期：v.128,no.33(August 23, 2006)
• ISSN：1520-5126

文摘

Glycosylation reactions using N-benzyl-2,3-trans-oxazolidinones as the glycosyl donors were shown to be highly -selective. Advantages of the donor include facile preparation in gram-scale preparation and simple deprotection procedures. Subsequently, a one-pot oligosaccharide synthesis involving 1,2-cis glycosidic linkages was demonstrated using the novel glycosyl donors.