Highly Monodisperse MIII-Based soc-MOFs (M = In and Ga) with Cubic and Truncated Cubic Morphologies
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- 作者：Maolin Pang ; Amy J. Cairns ; Yunling Liu ; Youssef Belmabkhout ; Hua Chun Zeng ; Mohamed Eddaoudi
- 刊名：The Journal of the American Chemical Society
- 出版年：2012
- 出版时间：August 15, 2012
- 年：2012
- 卷：134
- 期：32
- 页码：13176-13179
- 全文大小：326K
- 年卷期：v.134,no.32(August 15, 2012)
- ISSN：1520-5126
文摘
In this work, we carry out an investigation on shape-controlled growth of InIII- and GaIII-based square-octahedral metal鈥搊rganic frameworks (soc-MOFs). In particular, controllable crystal morphological evolution from simple cubes to complex octadecahedra has been achieved, and resultant highly uniform crystal building blocks promise new research opportunities for preparation of self-assembled MOF materials and related applications.