Catalytic Enantioselective Hetero-Diels-Alder Reactions of an Azo Compound

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• 作者：Masanori Kawasaki ; Hisashi Yamamoto
• 刊名：Journal of the American Chemical Society
• 出版年：2006
• 出版时间：December 27, 2006
• 年：2006
• 卷：128
• 期：51
• 页码：16482 - 16483
• 全文大小：36K
• 年卷期：v.128,no.51(December 27, 2006)
• ISSN：1520-5126

文摘

This communication describes studies in which an azo hetero-Diels-Alder adduct was furnished in high regio- and enantioselectivity using azopyridine as a reagent and silver as a catalyst. The obtained hetero-Diels-Alder adduct was easily converted to the corresponding chiral 1,4-diamino alcohol.