Discrimination of Active Palladium Sites in Catalytic Liquid-Phase Oxidation of Benzyl Alcohol
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- 作者：Davide Ferri ; Cecilia Mondelli ; Frank Krumeich ; Alfons Baiker
- 刊名：Journal of Physical Chemistry B
- 出版年：2006
- 出版时间：November 23, 2006
- 年：2006
- 卷：110
- 期：46
- 页码：22982 - 22986
- 全文大小：296K
- 年卷期：v.110,no.46(November 23, 2006)
- ISSN：1520-5207
文摘
Knowledge of the structure of active sites is a prerequisite for the rational design of solid catalysts. Usingsite-selective blocking by CO and isotope labeling combined with in situ attenuated total reflection infrared(ATR-IR) spectroscopy, we were able to discriminate the different sites involved in the liquid-phase oxidationof benzyl alcohol on Pd/Al2O3. The main reaction, that is, the oxidative dehydrogenation of the alcohol to thecorresponding aldehyde, showed only little dependence on structure and occurred on all exposed Pd faces,whereas the undesired product decarbonylation occurred preferentially on hollow sites on (111) Pd faces.This explains why specific blocking of the latter sites, as realized in the industrially used Pd-Bi/Al2O3 catalysts,leads to improved catalytic performance.