Synthesis of Tungsten Complexes Containing an Intramolecularly Coordinated Alkyne Group
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- 作者：Murray V. Baker and Simon K. Brayshaw
- 刊名：Organometallics
- 出版年：2004
- 出版时间：July 19, 2004
- 年：2004
- 卷：23
- 期：15
- 页码：3749 - 3751
- 全文大小：55K
- 年卷期：v.23,no.15(July 19, 2004)
- ISSN：1520-6041
文摘
Irradiation of cyclopentadienyltungsten carbonyl complexes bearing a pendant alkyne group promoted intramolecular displacement of CO by the alkyne.The resulting complexes, which contain an intramolecularly coordinated alkyne group, were characterized by1H and 13C NMR spectroscopy.