A Hybrid Consisting of Coordination Polymer and Noncovalent Organic Networks: A Highly Ordered 2-D Phenol Network Assembled by Edge-to-Face 
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- 作者：Jung Woo Ko ; Kil Sik Min ; and Myunghyun Paik Suh
- 刊名：Inorganic Chemistry
- 出版年：2002
- 出版时间：April 22, 2002
- 年：2002
- 卷：41
- 期：8
- 页码：2151 - 2157
- 全文大小：376K
- 年卷期：v.41,no.8(April 22, 2002)
- ISSN：1520-510X
文摘
A 2-D metal-organic open framework having 1-D channels, [Cu(C10H26N6)]3[C6H3(COO)3]2·18H2O (1), was constructedby the self-assembly of the Cu(II) complex of hexaazamacrocycle A (A = C10H26N6) with sodium 1,3,5-benzenetricarboxylate (BTC3-) in DMSO-H2O solution. 1 crystallizes in the trigonal space group P
with a = b =17.705(1) Å, c = 6.940(1) Å, 
= 
= 90
, 
= 120, V = 1884.0(3) Å3, Z = 1, and 
calcd = 1.428 g cm-3. TheX-ray crystal structure of 1 indicates that each Cu(II) macrocyclic unit binds two BTC3- ions in a trans position andeach BTC3- ion coordinates three Cu(II) macrocyclic complexes to form 2-D coordination polymer layers withhoneycomb cavities (effective size 8.1 Å), and the layers are packed to generate 1-D channels perpendicularly tothe 2-D layers. Solid 1 binds guest molecules such as MeOH, EtOH, and PhOH with different binding constantand capacity. By the treatment of 1 with aqueous solution of phenol, a hybrid solid [Cu(C10H26N6)]3[C6H3(COO)3]2·9PhOH·6H2O (2) was assembled. 2 crystallizes in the trigonal R3 space group with a = b = 20.461(1) Å, c =24.159(1) Å, = = 90, = 120, V = 8759.2(7) Å3, Z = 3, and calcd = 1.280 g cm-3. In 2, highly ordered2-D noncovalent phenol layers are formed by the edge-to-face 
- interactions between the phenol moleculesand are alternately packed with the coordination polymer layers in the crystal lattice.
with a = b =17.705(1) Å, c = 6.940(1) Å, = = 90, = 120, V = 1884.0(3) Å3, Z = 1, and calcd = 1.428 g cm-3. TheX-ray crystal structure of 1 indicates that each Cu(II) macrocyclic unit binds two BTC3- ions in a trans position andeach BTC3- ion coordinates three Cu(II) macrocyclic complexes to form 2-D coordination polymer layers withhoneycomb cavities (effective size 8.1 Å), and the layers are packed to generate 1-D channels perpendicularly tothe 2-D layers. Solid 1 binds guest molecules such as MeOH, EtOH, and PhOH with different binding constantand capacity. By the treatment of 1 with aqueous solution of phenol, a hybrid solid [Cu(C10H26N6)]3[C6H3(COO)3]2·9PhOH·6H2O (2) was assembled. 2 crystallizes in the trigonal R3 space group with a = b = 20.461(1) Å, c =24.159(1) Å, = = 90, = 120, V = 8759.2(7) Å3, Z = 3, and calcd = 1.280 g cm-3. In 2, highly ordered2-D noncovalent phenol layers are formed by the edge-to-face - interactions between the phenol moleculesand are alternately packed with the coordination polymer layers in the crystal lattice.