Electrochemistry of Group VI Metal Carbonyl Compounds Containing 1,1'-Bis(diphenylphosphino)ferrocene

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• 作者：Amanda C. Ohs ; Arnold L. Rheingold ; Michael J. Shaw ; and Chip Nataro
• 刊名：Organometallics
• 出版年：2004
• 出版时间：September 27, 2004
• 年：2004
• 卷：23
• 期：20
• 页码：4655 - 4660
• 全文大小：106K
• 年卷期：v.23,no.20(September 27, 2004)
• ISSN：1520-6041

文摘

The oxidative electrochemistry of a variety of homo- and bimetallic group VI metal carbonylcompounds containing 1,1'-bis(diphenylphosphino)ferrocene (dppf) with the general formulasM(CO)₅(dppf) (1a-c), M(CO)₄(dppf) (2a-c), and (CO)₅M(dppf)M'(CO)₅ (3a-f) (M, M' = Cr,Mo, W) was investigated. The effect of the group VI metal and the coordination mode of thedppf ligand on the potential at which the oxidation of the group VI metals and the ferrocenebackbone of dppf occurred was examined.