Rh Catalyzed C鈥揌 Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of Bromoarenes

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• 作者：Frederic W. Patureau ; Corinna Nimphius ; Frank Glorius
• 刊名：Organic Letters
• 出版年：2011
• 出版时间：December 16, 2011
• 年：2011
• 卷：13
• 期：24
• 页码：6346-6349
• 全文大小：833K
• 年卷期：v.13,no.24(December 16, 2011)
• ISSN：1523-7052

文摘

A Rh catalyzed, no-chelate-assisted C鈥揌 activation/oxidative olefination reaction of bromoarenes has been discovered, in which the latter ones seem to act as a substrate, terminal oxidant, and catalyst modifier.