Development of Solid-State Emissive Materials Based on Multifunctional o-Carborane–Pyrene Dyads
详细信息 查看全文
- 作者：Kenta Nishino ; Hideki Yamamoto ; Kazuo Tanaka ; Yoshiki Chujo
- 刊名：Organic Letters
- 出版年：2016
- 出版时间：August 19, 2016
- 年：2016
- 卷：18
- 期：16
- 页码：4064-4067
- 全文大小：284K
- 年卷期：0
- ISSN：1523-7052
文摘
The molecular design based on o-carborane dyads is described for preparing multifunctional luminescent molecules such as dual emissions, aggregation and crystallization-induced emission enhancements, and luminescent color changes. The pyrene-substituted o-carborane dyads were synthesized via the insertion reaction between decaborane and 1-ethynylpyrene in the presence of Lewis base in a good yield. Finally, extremely bright luminescent compounds with solid-state emission properties (ΦPL > 0.99) were obtained.