A Conducting Coordination Polymer Based on Assembled Cu9 Cages

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• 作者：Salomé ; Delgado ; Pablo J. Sanz Miguel ; José ; L. Priego ; Reyes Jimé ; nez-Aparicio ; Carlos J. Gó ; mez-Garcí ; a ; Fé ; lix Zamora
• 刊名：Inorganic Chemistry
• 出版年：2008
• 出版时间：October 20, 2008
• 年：2008
• 卷：47
• 期：20
• 页码：9128-9130
• 全文大小：157K
• 年卷期：v.47,no.20(October 20, 2008)
• ISSN：1520-510X

文摘

We report on a novel highly semiconducting 1D coordination polymer architecture obtained by the reaction of a Cu^II salt with 2,2′-dipyridyldisulfide under microwave solvothermal conditions. This reaction proceeds with an unusual C−S and S−S bond cleavage of the 2,2′-dipyridyldisulfide ligand. The unprecedented architecture of this coordination polymer consists of a 1D chain formed by the assembling of Cu₉ cluster cages. The electrical conductivity behavior of this novel material suggests new perspectives for the use of coordination polymers as electrical conducting materials.