Direct Synthesis of Arylketones by Nickel-Catalyzed Addition of Arylboronic Acids to Nitriles

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• 作者：Ying-Chieh Wong ; Kanniyappan Parthasarathy ; Chien-Hong Cheng
• 刊名：Organic Letters
• 出版年：2010
• 出版时间：April 16, 2010
• 年：2010
• 卷：12
• 期：8
• 页码：1736-1739
• 全文大小：186K
• 年卷期：v.12,no.8(April 16, 2010)
• ISSN：1523-7052

文摘

A convenient and efficient method for the synthesis of various arylketones by nickel-catalyzed addition of arylboronic acids to nitriles is described. A catalytic cycle involving Ni(II) species as the catalytic intermediates is proposed to account for the present catalytic reaction.