Supramolecular Templating Approach for the Solvent-Free Synthesis of Open-Framework Metal Oxalates

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• 作者：Furong Guo ; Cheng Chen ; Kangcai Wang ; Qinghua Zhang ; Zhien Lin
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：August 15, 2016
• 年：2016
• 卷：55
• 期：16
• 页码：7817-7819
• 全文大小：285K
• 年卷期：0
• ISSN：1520-510X

文摘

A series of open-framework metal oxalates (metal = Zn, Co, Mn, Bi, In) were prepared under solvent-free conditions by a supramolecular templating approach. These compounds have cationic, anionic, and neutral frameworks with pore apertures ranging from small 8-membered rings (8 MRs) to extra-large 16 and 20 MRs. The zinc oxalate exhibits a proton conductivity of 2.6 × 10^–3 S cm^–1 at 60 °C under 98% relative humidity.