Homochiral Zn and Cd Coordination Polymers Containing Amino Acid-Tetrazole Ligands

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• 作者：Zhi-Rong Qu ; Hong Zhao ; Xi-Sen Wang ; Yong-Hua Li ; Yu-Mei Song ; Yu-juan Liu ; Qiong Ye ; Ren-Gen Xiong ; Brendan F. Abrahams ; Zi-Ling Xue ; and Xiao-Zeng You
• 刊名：Inorganic Chemistry
• 出版年：2003
• 出版时间：December 1, 2003
• 年：2003
• 卷：42
• 期：24
• 页码：7710 - 7712
• 全文大小：195K
• 年卷期：v.42,no.24(December 1, 2003)
• ISSN：1520-510X

文摘

The reactions of (S)-3-cyanophenylalanine with NaN₃ in thepresence of H₂O and Lewis acids (ZnCl₂ and CdCl₂) afford twounprecedented 3D homochiral networks, mono[(S)-5-(3-tetrazoyl)-phenylalaninato]zinc(II) (1) and mono[(S)-5-(3-tetrazoyl)-phenylalaninato]cadmium(II) monoaqua(II) (2), respectively. The twocompounds are isostructural with noninterpenetrated SrAl₂ topology.The structure of these coordination polymers gives new insightinto Sharpless' reaction of chiral 5-substituted 1H-tetrazole andhomochiral supramolecular array constructions.