Direct Fabrication of Densely Packed Idiomorphic Li4Ti5O12 Crystal Layers on Substrates by Using a LiCl鈥揘aCl Mixed Flux and Their Additive-Free Electrode Characteristi

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• 作者：Nobuyuki Zettsu ; Yusuke Mizuno ; Hiroki Kojima ; Kunio Yubuta ; Takuya Sakaguchi ; Toshiya Saito ; Hajime Wagata ; Shuji Oishi ; Katsuya Teshima
• 刊名：Crystal Growth & Design
• 出版年：2014
• 出版时间：November 5, 2014
• 年：2014
• 卷：14
• 期：11
• 页码：5634-5639
• 全文大小：407K
• ISSN：1528-7505

文摘

Thin layers of densely packed idiomorphic Li₄Ti₅O₁₂ crystals were prepared directly on a Pt substrate by using a LiCl鈥揘aCl mixed flux. The thin film of colloidal anatase nanoparticles with an 鈭?0 nm diameter was fully converted into Li₄Ti₅O₁₂ crystals with a diameter of 100鈥?00 nm having polyhedral shapes with well-defined {111} faces during the evaporation-driven flux growth. Cross-sectional structure analysis revealed that the interface between the crystals and the substrate seemed to be atomically bonded. Galvanometric charge and discharge properties strongly supported our consideration of interface formation. The Li₄Ti₅O₁₂ crystal layer exhibited a large capacity close to its theoretical value under 0.1C rate with no assistance from additional electroconductive materials and binders, meaning that the interfaces provide seamless charge transportation pathways. We also addressed the formation mechanism of the Li₄Ti₅O₁₂ crystal layer accompanied by the experimental results of in situ X-ray diffraction, thermogravimetric and differential thermal analysis, and scanning electron microscopy observation.