Hollow Co0.85Se Nanowire Array on Carbon Fiber Paper for High Rate Pseudocapacitor
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- 作者：Abhik Banerjee ; Sumit Bhatnagar ; Kush Kumar Upadhyay ; Prasad Yadav ; Satishchandra Ogale
- 刊名：ACS Applied Materials & Interfaces
- 出版年：2014
- 出版时间：November 12, 2014
- 年：2014
- 卷：6
- 期：21
- 页码：18844-18852
- 全文大小：658K
- ISSN：1944-8252
文摘
A supercapacitor electrode is fabricated with Co0.85Se hollow nanowires (HNW) array, which is synthesized by wet chemical hydrothermal selenization of initially grown cobalt hydroxyl carbonate nanowires on conductive CFP. The dense self-organized morphology of Co0.85Se HNWs is revealed by scanning/transmission electron microscopy. The as-synthesized Co0.85Se HNWs possess high pseudocapacitive property with high capacitance retention and high durability. The areal capacitance value is seen to vary from 929.5 to 600 mF cm鈥? (60% retention) as the current density is increased from 1 to 15 mA cm鈥?, an increase of a factor of 15. Based on mass loading, this corresponds to a very high gravimetric capacitance of 674 (for 2 mA cm鈥? or 1.48 Ag鈥?) and 444 Fg1鈥?/sup> (for 15 mA cm鈥? or 11 A g鈥?) in a full-cell configuration with the Co0.85Se HNWs as cathode and activated carbon as anode (asymmetric configuration) promising results are obtained.