Multicomponent Adsorption and Desorption of BTX Compounds Using Coconut Shell Activated Carbon: Experiments, Mathematical Modeling, and Numerical Simulation

详细信息    查看全文

• 作者：Adriana Dervanoski Luz ; Selene Maria de Arruda Guelli Ulson de Souza ; Cleuzir da Luz ; Ricardo Vicente de Paula Rezende ; Ant么nio Augusto Ulson de Souza
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：2013
• 出版时间：June 12, 2013
• 年：2013
• 卷：52
• 期：23
• 页码：7896-7911
• 全文大小：955K
• 年卷期：v.52,no.23(June 12, 2013)
• ISSN：1520-5045

文摘

A numerical and experimental study of the monocomponent and multicomponent adsorption and desorption of BTX compounds (benzene, toluene, and o-xylene) in a batch reactor and fixed-bed column was carried out in aqueous solution at 23 掳C, using coconut shell activated carbon as the adsorbent. The monocomponent Langmuir isotherm model best represented the experimental results (average R² = 0.9952) and the multicomponent Langmuir model, using the multicomponent parameters, represented the multicomponent data obtained in a fixed-bed column better than the monocomponent model. The equations which describe the phenomenology were discretized using the Finite Volumes Method with the WUDS and CDS formulations. The results for the monocomponent breakthrough curves obtained through simulation showed good agreement when compared with the experimental data (maximum error of 11.52%). For the monocomponent breakthrough curves the greatest deviation was observed for the compound which had the least affinity for the solid phase (benzene). The best results for the desorption of the BTX compounds from the adsorbent were obtained using ethanol as the desorbent solvent, and the average removal percentages in three cycles of regeneration in the column were 90% for benzene, 82% for toluene, and 78% for o-xylene.