Progress in High-Capacity Core–Shell Cathode Materials for Rechargeable Lithium Batteries

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• 作者：Seung-Taek Myung ; Hyung-Joo Noh ; Sung-June Yoon ; Eung-Ju Lee ; Yang-Kook Sun
• 刊名：The Journal of Physical Chemistry Letters
• 出版年：2014
• 出版时间：February 20, 2014
• 年：2014
• 卷：5
• 期：4
• 页码：671-679
• 全文大小：648K
• ISSN：1948-7185

文摘

High-energy-density rechargeable batteries are needed to fulfill various demands such as self-monitoring analysis and reporting technology (SMART) devices, energy storage systems, and (hybrid) electric vehicles. As a result, high-energy electrode materials enabling a long cycle life and reliable safety need to be developed. To ensure these requirements, new material chemistries can be derived from combinations of at least two compounds in a secondary particle with varying chemical composition and primary particle morphologies having a core鈥搒hell structure and spherical cathode-active materials, specifically a nanoparticle core and shell, nanoparticle core and nanorod shell, and nanorod core and shell. To this end, several layer core鈥搒hell cathode materials were developed to ensure high capacity, reliability, and safety.